Drain all but 2 tablespoons of fat from the pan; add onions, carrots, celery, garlic, tomato paste, 1 teaspoon herbes de Provence and a light sprinkling of salt. Saute vegetables to soften them slightly, about 3-4 minutes. Add wine, then stock, stirring with a wooden spoon to loosen browned bits from the bottom of the pan. Bring liquid to a simmer, transfer vegetables and liquid to deep braising pan large enough to hold shanks in a single layer. Add shanks, season with salt, pepper and herbes de Provence.